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Section III · Topic guide

Rates of reaction & kinetics

Section III — Sciences · a free, hand-written guide with worked reasoning and adaptive practice that finds your weak spots.

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The short answer

What changes a reaction's speed — and how Section III tests it with graphs and data.

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Free interactive lesson

Try the reasoning style

Section I · Humanities & Social SciencesIllustrative example

We treat forgetting as a failure — a lapse to be patched with reminders and records. Yet a mind that kept everything could not think; it would drown in the undifferentiated noise of every moment it had ever lived. To forget is not so much to lose information as to decide, mostly without our noticing, what was never worth keeping.

The author's argument relies most directly on which unstated assumption?

Pick an option to see how the tutor reasons to the answer — not just whether you were right.

How to reason to the answer

Not quite — the answer is B.

Work backwards from the conclusion: a mind that ‘kept everything’ supposedly ‘could not think.’ That only follows if thinking means leaving most of experience out — so B is the premise the argument quietly rests on. A raises reliability, which the passage never weighs; C contradicts ‘mostly without our noticing’; D smuggles in a claim about intellect the passage never makes. The question rewards finding the hidden premise, not recalling a fact.

Kinetics is about how fast, not how far. Section III rarely asks you to recall a rate law — it gives you data or a graph and asks you to reason about the speed.

Collision theory in a line

Reactions go faster when particles collide more often or more energetically. Everything that speeds a reaction does one of those two things.

Reactant concentration over time

Concentration falls fast at first, then levels off as the reactant runs out.

The curve is steepest at t = 0 (most reactant → most collisions → fastest rate) and flattens as [A] drops — the rate slows itself down.

What speeds a reaction — and why

Increases the rate

  • ↑ Concentration / pressure (more collisions)
  • ↑ Temperature (faster, harder collisions)
  • ↑ Surface area (more contact)
  • Add a catalyst (lower activation energy)

What a catalyst does NOT do

  • Does not get used up
  • Does not change the products
  • Does not shift the equilibrium position
  • Only provides a lower-energy pathway

Reading the slope

Two questions ask about the graph above: where is the reaction fastest, and what is happening to the rate over time?

Check yourself

On the concentration-time graph above, how does the reaction rate change as time goes on?

Key takeaways

  • Kinetics = how fast; equilibrium = how far. Don't confuse them.
  • Faster rate = more frequent or more energetic collisions.
  • On a concentration-time graph, rate is the gradient — steepest at the start.
  • A catalyst lowers activation energy without being consumed or shifting equilibrium.

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4 min read · Concept